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- Gaspar Vladi (Appear in Season 2 - 4) (New, Born & Hero)
Ayane Sakura 
Irina Shidou
Maaya Uchida
Rossweisse
Ai Kakuma- Sairaorg Bael (S2 - S4)
Yūichi Nakamura 
Vali Lucifer
Ryouta Oosaka
Azazel
Rikiya Koyama
Kuroka
Minami Takahashi
Aika Kiryuu
Haruka Yamazaki
Genshirou Saji
Yuuichi Iguchi- Freed Sellzen (S1, S2)
Yoshitsugu Matsuoka - Tsubaki Shinra (S1, S2)
Akiko Kimura - Souna Shitori (S2 & S3)
Natsumi Takamori - Riser Phenex (S1, S4)
Takehito Koyasu - Yuuma Amano (Raynare) (S1) / Raynare (S3 & S4)
Hitomi Nabatame 
Serafall Leviathan
Ai Shimizu- Leonardo (S4) / Misia Bael (S4)
Airi Ootsu - Milicas Gremory (S3 & S4)
Ari Ozawa - Ravel Phoenix (S3 & S4)
Asuka Nishi - Jeanne (S4)
Ayaka Asai - Aika Kiriyuu (S2 - S4)Haruka Yamazaki
- Naud Gamigin (S4)
Hajime Iijima - Cattleya Leviathan (S2)
Harumi Sakurai - Siegfried (S4)
Jun Fukushima - Creuserey Asmodeus (S3)
Hiromichi Tezuka - Kokabiel (S2)
Hiroki Yasumoto - Ajuka Beelzebub (S3, S4)
Jun'ichi Yanagita 
Sirzechs Lucifer
Junichi Suwabe- Heracles (S4)
Jun Kasama - Regulus (S4)
Kouhei Amasaki - Shalba Beelzebub (S3 & 4)
Ken Narita - Arthur Pendragon (S3 & S4)
Kaito Ishikawa - Venerana Gremory (S3)
Mari Shiraishi - Bikou (S3 & S4)
Makoto Yasumura - Cao Cao (S4)
Kousuke Toriumi - Le Fay Pendragon (S4)
Minami Shinoda - Hades (S4)
Masuo Amada - Odin (S4)
Shinpachi Tsuji - Rudiger Rosenkreutz (S4)
Satoshi Hino - Alboin (S2, S3, S4)
Ryouta Takeuchi - Tannin (S3, S4)
Tarou Yamaguchi - Georg (S4)
Shou Nogami - Lord Gremory (S2, S3, S4)
Show Hayami - Vritra (S4)
Toshiki Iwasawa - Michael (S2, S3)
Yoshimasa Hosoya - Yasaka (S4)
Yō Taichi